准噶尔盆地白垩系烃源岩与原油地球化学特征     

张兴雅  赵龙  党思思  孙平安  曹剑 《矿物岩石地球化学通报》2015,(3)

准噶尔盆地白垩系含油气系统理论上具备一定的勘探能力,但研究程度较低。为加深对该问题的理解,分析了白垩系的烃源岩和原油地球化学特征,并进一步结合地质背景,探讨了勘探潜力。结果发现,白垩系发育有一定数量和规模的泥质烃源岩,存在有机碳TOC含量大于1.0%的样品,类型以Ⅱ型为主,目前主体处于低成熟—成熟演化阶段,因此可望具有一定的生烃,特别是生油潜力。油源对比发现白垩系的确有过原油生成,典型地球化学特征表现为轻碳同位素(-29.6‰~-27.9‰)、低Pr/Ph值(0.54~1.01)、高伽马蜡烷丰度(伽马蜡烷/C30藿烷=0.29~0.53),反映属于一类还原和盐度环境中有机质所生原油。这类原油主要分布在盆地南缘白垩系烃源岩的沉积中心区,表现出源控特征。这些认识可供国内外其他白垩系油气地质研究时类比考察。  相似文献   

Characterization of low-molecular-weight organic acids isolated from the Toarcian argillite pore water (Tournemire site,France)     

《Comptes Rendus Geoscience》2015,347(2):77-83

Bacterial activity in the near-field environment of radioactive waste disposal facilities in deep argillaceous rocks is currently under investigation. Bacterial development could be enhanced by the availability of low-molecular-weight organic acids (LMWOA) dissolved in the pore water of clayey rocks. This study firstly aimed at isolating and characterizing the LMWOA of the Toarcian argillite from the Tournemire Underground Research Laboratory (France, Aveyron). It also aimed at assessing the disturbing effects that could be induced by a disposal facility on the type and release of LMWOA (exposure to oxygen, alkaline pH, temperature increase). Under the experimental conditions investigated at 60 °C, the mean dissolved organic carbon (DOC) is about 15 mg L⁻¹ with a LMWOA proportion of 35 %. The main LMWOA are composed of formate, fumarate, propionate, acetate, and lactate. DOC is mainly influenced by both temperature and pH increases, whereas the LMWOA type nature and release are more specifically affected by the exposure to oxygen.  相似文献   

超压对川东南地区五峰组-龙马溪组页岩储层影响分析     

刘若冰 《沉积学报》2015,33(4):817-827

四川盆地东南部保存条件较好的五峰组-龙马溪组页岩普遍存在超压,且在其他地质条件相同的情况下,超压页岩储层相对于常压、低压储层具有更高的孔隙度.研究表明,富有机质页岩在适中的热演化过程中,由于烃类的大量生成,形成较多有机质孔隙,增加了页岩储层储集空间;另一方面,烃类大量生成造成的超压对页岩储层储集空间保存具有至关重要的作用.川东南五峰组-龙马溪组优质页岩储层孔隙以有机质孔、黏土矿物孔等塑性孔为主,且缺少刚性矿物颗粒支撑,易被上覆地层有效应力压实.但超压的存在对于页岩储层具有保护作用,抵消了上覆地层有效应力对页岩储层的机械压实,从而使已形成的页岩孔隙保存下来,使页岩储集空间得以保留.研究超压对页岩储层孔隙度影响机制以及超压页岩储层发育模式对于四川盆地五峰组-龙马溪组页岩气勘探、开发具有重要意义.  相似文献   

Methodological comparison for quantitative analysis of fossil and recently derived carbon in mine soils with high content of aliphatic kerogen     

《Organic Geochemistry》2015

In mine soil, quantification of soil organic carbon (OC) derived recently from biomass decomposition is complicated by the presence of fossil (geogenic) C derived from coal, oil shale, or similar material in the overburden. The only reliable method for such measurement is ¹⁴C analysis (i.e. radiocarbon dating) using instrumentation such as accelerator mass spectrometry, which is too expensive for routine laboratory analysis. We tested two previously used and two new methods for recent C quantification and compared them with ¹⁴C AMS radiocarbon dating as a reference using a set of soil samples (n = 14) from Sokolov, Czech Republic: (i) ¹³C isotope ratio composition, (ii) cross polarization magic angle spinning ¹³C nuclear magnetic resonance (CPMAS ¹³C NMR) spectroscopy, (iii) near infrared spectroscopy (NIRS) coupled with partial least squares regression and (iv) Rock–Eval pyrolysis. Conventional methods for OC determination (dry combustion, wet dichromate oxidation, loss-on-ignition) were also compared to quantify any bias connected with their use. All the methods provided acceptable recent carbon estimates in the presence of mostly aliphatic fossil C from kerogen. However, the most accurate predictions were obtained with two approaches using Rock–Eval pyrolysis parameters as predictors, namely (i) S₂ curve components and (ii) oxygen index (OI). The S₂ curve approach is based on the lower thermal stability of recent vs. fossil organic matter. The OI approach corresponded well with ¹³C NMR spectra, which showed that samples rich in recent C were richer in carboxyl C and O-alkyl C. These two methods showed the greatest potential as routine methods for recent C quantification.  相似文献   

星地多源数据的区域土壤有机质数字制图   总被引：4，自引：0，他引：4  

周银  刘丽雅  卢艳丽  马自强  夏芳  史舟 《遥感学报》2015,19(6):998-1006

土壤有机质(SOM)是全球碳循环、土壤养分的重要组成部分,精确估算土壤有机质含量具有重要意义。本文以中国东北—华北平原为研究区,收集了1078个土壤样本,以遥感数据(MODIS,TRMM和STRM数据)与土壤地面光谱数据为预测因子,运用基于树形结构的数据挖掘技术构建土壤有机质-环境预测因子模型进行数字土壤制图。通过不同建模样本数建模精度比较,选择300个样本数时的模型为最优模型。建模结果表明土壤光谱和气候因子是研究区SOM变异的主控因子,生物因子次之,而地形因子影响最小。预测结果经检验,RMSE为7.25,R2为0.69,RPD为1.53制图结果与基于第二次全国土壤普查数据的土壤有机质地图具有相似的分布规律,呈现SOM自东北向西南递减的趋势。通过比较分析发现,经过20年左右的土地开发与利用,研究区低SOM和高SOM含量土壤面积减少,而中等SOM含量土壤面积增加。  相似文献   

An assessment of chlorophyll-a concentration spatio-temporal variation using Landsat satellite data,in a small tropical reservoir     

Tatenda Dalu  Timothy Dube  P. William Froneman  Mwazvita T.B. Sachikonye  Bruce W. Clegg  Tamuka Nhiwatiwa 《国际地球制图》2015,30(10):1130-1143

Traditional approaches to monitoring aquatic systems are often limited by the need for data collection which often is time-consuming, expensive and non-continuous. The aim of the study was to map the spatio-temporal chlorophyll-a concentration changes in Malilangwe Reservoir, Zimbabwe as an indicator of phytoplankton biomass and trophic state when the reservoir was full (year 2000) and at its lowest capacity (year 2011), using readily available Landsat multispectral images. Medium-spatial resolution (30 m) Landsat multispectral Thematic Mapper TM 5 and ETM+ images for May to December 1999–2000 and 2010–2011 were used to derive chlorophyll-a concentrations. In situ measured chlorophyll-a and total suspended solids (TSS) concentrations for 2011 were employed to validate the Landsat chlorophyll-a and TSS estimates. The study results indicate that Landsat-derived chlorophyll-a and TSS estimates were comparable with field measurements. There was a considerable wet vs. dry season differences in total chlorophyll-a concentration, Secchi disc depth, TSS and turbidity within the reservoir. Using Permutational multivariate analyses of variance (PERMANOVA) analysis, there were significant differences (p < 0.0001) for chlorophyll-a concentration among sites, months and years whereas TSS was significant during the study months (p < 0.05). A strong positive significant correlation among both predicted TSS vs. chlorophyll-a and measured vs. predicted chlorophyll-a and TSS concentrations as well as an inverse relationship between reservoir chlorophyll-a concentrations and water level were found (p < 0.001 in all cases). In conclusion, total chlorophyll-a concentration in Malilangwe Reservoir was successfully derived from Landsat remote sensing data suggesting that the Landsat sensor is suitable for real-time monitoring over relatively short timescales and for small reservoirs. Satellite data can allow for surveying of chlorophyll-a concentration in aquatic ecosystems, thus, providing invaluable data in data scarce (limited on site ground measurements) environments.  相似文献   

乌鲁木齐市PM10,PM2.5和PM1.0浓度及分布变化特征研究     

韩茜  魏文寿  刘新春  钟玉婷 《沙漠与绿洲气象(新疆气象)》2015,9(1):32-38

利用GRIMM180气溶胶粒谱分析仪采集乌鲁木齐市PM10、PM2.5和PM1.0数据,研究表明:乌鲁木齐市气溶胶颗粒物质量浓度在进入采暖季后急剧增加,冬季颗粒物中细粒子含量最高,PM2.5/PM10可达77.6%,PM2.5/PM10,PM1.0/PM10,PM1.0/PM2.5三比值体现了颗粒物的分布特征,四季污染程度越高,细粒子含量越高。四季无降水日PM10、PM2.5、PM1.0的质量浓度和分布的日变化基本呈三峰三谷型,出现早—午—晚峰值,上午—下午—午夜后谷值,各季节峰谷值具体出现时间略有差别,由于冬季逆温层顶盖等因素的影响,冬季质量浓度和分布的日变化在此基础上多了两次波动。降水的发生对冬、春季质量浓度的影响大于夏、秋季,对不同粒径段粒子的分布影响有一定差别。  相似文献   

长江口外浮游植物死亡释放溶解有机质的降解及其溶氧消耗   总被引：2，自引：0，他引：2  

高小丰  吴莹  朱卓毅 《海洋与湖沼》2015,46(5):1010-1017

浮游植物光合作用产生的溶解有机质(dissolved organic matter,DOM)是海洋中溶解有机质的重要来源,浮游植物死亡后释放的新鲜溶解有机质活性高、数量大、生物可利用性高,其降解过程中对溶解氧(dissolved oxygen,DO)的消耗显著。但到目前为止,对此类溶解有机质的降解过程以及其耗氧情况还鲜有研究。本文基于2013年8月东海航次,对浮游植物(硅藻为主)死亡后释放的新鲜有机质进行人工受控培养,研究其降解过程及对DO的消耗,并评估该降解过程对低氧现象形成的贡献。研究发现:培养体系中溶解有机碳(dissolved organic carbon,DOC)和DO浓度皆随时间呈指数下降,总溶解态碳水化合物(total carbohydrate,TCHO)也出现明显降解;体系的初始DOC浓度越高,降解速率常数k(DOC)、k(DO)越大,k(DOC)受DOC浓度、活性以及DO浓度的影响;培养过程中细菌丰度明显增加,添加Hg Cl2的对比实验表明细菌在降解过程中起到重要作用。本文的研究结果表明,浮游植物死亡后释放的溶解有机质的快速降解及其对溶解氧的消耗,对长江口低氧环境的促成具有重要意义。  相似文献   

Microbial biomass response to different quantities and sources of organic matter in Brazilian coastal sediments          下载免费PDF全文

Cintia O. Quintana  Paula C. de Moraes  Marcos Y. Yoshinaga  Stuart G. Wakeham  Paulo Y. G. Sumida 《Marine Ecology》2015,36(3):766-779

This study investigates the benthic microbial responses to organic matter (OM) variations in quantity and sources in two shallow water bays (Fortaleza and Ubatuba Bays) on the SE coast of Brazil on six occasions during the year. The pelagic and benthic compartments of the bays were evaluated by: (i) nutrients and chlorophyll a (Chl a) in the water column; (ii) quantity and sources of OM in the sediment (Chl a, total organic carbon and total nitrogen and lipid biomarker composition); and (iii) microbial biomass in sediments as an indicator of active benthic response. Although there were changes in water‐column nutrients during the year, Chl a was fairly constant, suggesting a regular supply of microalgae‐derived OM to the sea bottom. Based on the composition of lipid biomarkers in sediments, OM sources were classified as mostly marine and with high contributions of labile (microalgae‐derived) OM. Labile OM composition varied from diatoms in the summer to phytoflagellates in the winter and tended to accumulate in areas protected by physical disturbances in one of the bays. Microbial biomass followed this trend and was 160% higher in protected than in exposed areas. This study suggests that the coupling between labile OM and benthic microbial biomass occurs primarily in protected areas, irrespective of the time of the year. Since meio‐ and macrofaunal assemblages depend upon secondary microbial production within the sediments, this coupling may have an important role for the benthic food‐web.  相似文献   

南极半岛东北海域表层沉积有机质来源及其沉积环境     

韩喜彬  赵军  初凤友  潘建明  唐灵刚  许冬  边叶萍  葛倩 《海洋学报》2015,37(8):26-38

采用气相色谱-质谱技术对南极半岛东北海域海底表层沉积物的总有机碳、有机质碳同位素(δ13 Corg)和生物标志化合物等进行了测试分析。研究区表层沉积物总有机碳TOC平均值高于现代深海沉积物中的平均含量。δ13 Corg的变化说明该海域有机碳来源呈海洋水生生物来源和陆源混合的特征。正构烷烃的峰型分布、主峰碳、饱和烃轻重比C-21/C+22和(C21+C22)/(C28+C29)、甾烷组合和藿烷组合证实研究区西部表层沉积物有机质来源以陆源高等植物为主,其陆源可能来自于附近的南极半岛和南舍得兰群岛;研究区东部表层沉积物有机质来源偏以海源为主,且以低等浮游生物、藻类及细菌生物等海源输入为主。碳优势指数(Carbon preference index,CPI)、奇偶优势指数(Odd-even Predominance,OEP)和甾烷C29ααα20S/(20S+20R)比值显示研究区D1-7站位和D5-9沉积物有机质演化程度较高,D5-2和D2-4站位的有机质演化程度低,其他站位介于中间状态。饱和烃中姥鲛烷、植烷及其比值(Pr/Ph)等组合显示研究区西部以氧化-弱还原的沉积环境为主,其可能是受高温低盐别林斯高晋海水流和附近火山喷发的影响所致;研究区东部以还原—强还原沉积环境为主,可能是受低温高盐的威德尔底层水(WSBW)和威德尔海深层水(WSDW)影响所致。  相似文献